Piperazinediium dioxamate

نویسندگان

  • S. Murugavel
  • R. Selvakumar
  • S. Govindarajan
  • P. S. Kannan
  • A. SubbiahPandi
چکیده

The title compound, C(4)H(12)N(2) (2+)·2C(2)H(2)NO(3) (-), contains a network of doubly protanated piperazinium cations (lying about centres of inversion) and dioxamate anions. The piperazinium dication adopts a typical chair conformation. The crystal structure is stabilized by cation-to-anion N-H⋯O and anion-to-anion N-H⋯O hydrogen bonds.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Piperazine-1,4-diium bis­(pyridine-2,6-dicarboxyl­ato-κ3 O 2,N,O 6)cobaltate(II) tetra­hydrate

The asymmetric unit of the title complex, (C(4)H(12)N(2))[Co(C(7)H(3)NO(4))(2)]·4H(2)O, consists of one piperazinediium dication, one [Co(py-2,6-dc)(2)](2-) dianion (where py-2,6-dc is pyridine-2,6-dicarboxyl-ate) and four water mol-ecules. The piperazinediium cation adopts a chair conformation and the Co(II) ion is six-coordinated in an N(2)O(4) environment, having a distorted octa-hedral geom...

متن کامل

Diethyl N,N′-(p-phenylene)dioxamate

In the crystal structure, the mol-ecule of the title compound, C(14)H(16)N(2)O(6), is located on an inversion centre. The amide -NHCO- plane makes a dihedral angle of 34.08 (9)° with the benzene ring. The mol-ecules are connected via inter-molecular O-H⋯N hydrogen bonds into a two-dimensional network parallel to the bc plane. An intramolecular N-H⋯O hydrogen bond is also observed.

متن کامل

Hydrogen-Bonding Motifs in Piperazinediium Salts

Four novel organic salts of piperazine and 2-methylpiperazine with p-toluenesulfonic acid and chloroacetic acid have been synthesized and structurally characterized. The hydrogen-bonding ring synthons that exist between the cation/anion pairs are compared and contrasted alongside database results.

متن کامل

Tris(piperazinediium) phosphatododeca­molybo(V,VI)phosphate

The title compound, (C(4)H(12)N(2))(3)[PMo(12)O(40)] or (H(2)pip)(3)[PMo(12)O(40)] (pip is piperazine), was prepared under hydro-thermal conditions. The asymmetric unit contains one-sixth of a mixed-valent Mo(V,VI) pseudo-Keggin-type [PMo(12)O(40)](6-) anion and half a piperazinediium cation, (H(2)pip)(2+). The discrete Keggin-type [PMo(12)O(40)](6- )anion has site symmetry and the three (H(2)p...

متن کامل

N-Methyl­piperazinediium penta­chloridoanti­monate(III) monohydrate

The asymmetric unit of the title compound, (C(5)H(14)N(2))[SbCl(5)]·H(2)O, consists of an N-methyl-piperazinediium cation, a penta-chloridoanti-monate anion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment, and one solvent water mol-ecule. The crystal structure is stabilized by inter-molecular N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009